The mechanism of Troger's base formation probed by electrospray ionization mass spectrometry

datacite.alternateIdentifier.issn	0022-3263
datacite.creator	Abella, C.A.M.
datacite.creator	Benassi, M.
datacite.creator	Santos, L.S.
datacite.creator	Eberlin, M.N.
datacite.creator	Coelho, F.
datacite.date.issued	2007
datacite.title	The mechanism of Troger's base formation probed by electrospray ionization mass spectrometry	en
dc.date.accessioned	2008-04-08T21:18:24Z
dc.date.available	2008-04-08T21:18:24Z
dc.description	Santos, L.S. Instituto de Química de Recursos Naturales, Universidad de Talca, P.O. Box 747, Talca, Chile.	en
dc.description.abstract	Using direct infusion electrospray ionization mass and tandem mass spectrometric experiments [ESI-MS(/MS)], we have performed on-line monitoring of some reactions used to form Tröger's bases. Key intermediates, either as cationic species or as protonated forms of neutral species, have been intercepted and characterized. The role of urotropine as the methylene source in these reactions has also been accessed. Reaction pathways shown by ESI-MS(/MS) have been probed by gas-phase ion/molecule reactions, and an expanded mechanism for Tröger's base formation based on the mass spectrometric data has been elaborated.	en
dc.format.extent	2946 bytes
dc.format.mimetype	text/html
dc.identifier.citation	Journal of Organic Chemistry 72 (11):4048 - 4054	en
dc.identifier.uri	https://repositorio.utalca.cl/repositorio/handle/1950/4769
dc.language	en
dc.publisher	American Chemical Society Journals	en
oaire.resourceType	Artículo	en
utalca.index	Artículo de publicación ISI

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