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Item Biotransformation of Stypotriol triacetate by Aspergillus nigerAutores: Areche, C (Areche, Carlos)1;; Vaca, I (Vaca, Inmaculada)1;; Labbe, P (Labbe, Pamela)1;; Soto-Delgado, J (Soto-Delgado, Jorge)2;; Astudillo, L (Astudillo, Luis)3;; Silva, M (Silva, Mario)4;; Rovirosa, J (Rovirosa, Juana)1;; San-Martin, A (San-Martin, Aurelio)1Biological transformation of the meroditerpenoid, stypotriol triacetate (1) by the fungi Aspergillus niger, Cunninghamella elegans, Gibberella fujikuroi and Mucor plumbeus was studied. The incubation of 1 with A. niger yielded the new compound 6',14-diacetoxy-stypol-4,5-dione (2) whose structure was established by (1)H, (13)C and 2D NMR and supported by DFT/GIAO. (C) 2011 Elsevier B.V. All rights reserved.